Webbismuthinidene complex was isolated as red single crystalsin 10%yield. To the best of our knowledge, this is the first exam-ple of aBe0 complex being used as areducing agent.Surpris-ingly,hexane- and toluene-soluble 2 can also act as aligand-transfer reagent (Scheme 3). Indeed, red crystals of compound WebThe hypothetical [BiPh] − anion obtained by a one-electron reduction from the respective bismuthinidene is proposed as a basis for constructing single-molecule magnets (SMMs) consisting purely of main-group elements. Based on high-level quantum-chemical calculations, the [BiPh] − anion is predicted to be a SMM with an effective barrier of 6418 …
A “non-magnetic” triplet bismuthinidene enabled by …
WebOct 5, 2015 · It is clear that the structure of the reduced products (bismuthinidene versus dibismuthene) is ligand-dependent and … WebDOI: 10.1039/d3sc00917c Corpus ID: 258017944; Planar bismuth triamides: a tunable platform for main group Lewis acidity and polymerization catalysis @article{Hannah2024PlanarBT, title={Planar bismuth triamides: a tunable platform for main group Lewis acidity and polymerization catalysis}, author={Tyler J. Hannah and W. … oak grove riverside county
Phan T. Truong - Visiting Assistant Professor - LinkedIn
WebThis bis ‐ (carbone) ligand is an effective scaffold for forming monometallic (Ni and Pd) and trinuclear heterometallic complexes with Au–Pd–Au, Au–Ni–Au, and Cu–Ni–Cu configurations. WebThe molecular structure of 5b has been determined by X-ray crystallography which shows the bismuth atom in a pseudo trigonalbipyramidal geometry with the nitrogen atom lying above the plane defined by the two manganese and the oxygen atoms in an apical position. WebWe report the generation, spectroscopic characterization, and computational analysis of the first free (non-stabilized) organometallic bismuthinidene, BiMe. The title compound was generated in situ from BiMe 3 by … mailing christmas cards usps